You are not understanding what's being said here. The Volt has a passive locking system "with key fob proximity detection".
If the Fob is near the car the rear hatch WILL be able to be opened by pressing the release button. Lock the car and GET THE FOB AWAY FROM THE CAR!! put it in your house or give it to someone and tell them to get 15 - 25 feet or more away from the car. THEN attempt to open the hatch. I think you will find it is locked (actually it is "always" locked) when no key fob is detected in close proximity to the car.