in my opinion this is the most important mod we will be able to do for the Volt. keep up the investigative work!
Here are a few images showing its location, the connector pin out and where it connects on the main connectors
Remove The Front Right Side Wheelhouse Front Liner (Front Wheelhouse Front Liner Replacement
Disconnect the electrical connector.
Unsnap the temperature sensor from the air deflection/baffle.
To remove the front liner:
Remove the tyre and wheel assembly. Refer to Tyre and Wheel Removal and Installation .
1 Front Wheelhouse Liner Push-In Retainer - Front (Qty: 2)
2 Front Wheelhouse Liner Screw - Front (Qty: 4) Tighten to 3 N·m (27 lb in)
3 Front Wheelhouse Liner - Front Lower Screw (Qty: 3) Tighten 3 N·m (27 lb in)
4 Front Wheelhouse Liner - Front Lower Front Screw (Qty: 5) Tighten to 3 N·m (27 lb in)
5 Front Wheelhouse Liner - Front Procedure Disengage the upper interlocking retainers.
Here is the info on the actual connector
Harness Type: Forward Lamp
OEM Connector: 13543521
Service Connector: 12101856
Description: 2-Way F Metri-Pack 150 Series, Sealed (BK)
Terminal Part Information
Terminated Lead: Service by Connector Assembly - 12101856
Release Tool: J-38125-12A
Diagnostic Test Probe: J-35616-14 (GN)
The pins run to the Hybrid Hybrid Powertrain Control Module 2 X1
Code:
Pin Size Color Circuit Function
26 0.35 L-BU/GY 636 Outside Ambient Air Temperature Sensor Signal
40 0.35 BK/L-BU 61 Outside Ambient Temperature Sensor Low Reference
The Hybrind Powertrain Control module is under the passenger seat
Hope that helps. I'll keep digging to see what other useful stuff I can find.