TPMS is not 100% trustworthy
There is some previous posts here at this forum about the "Tire Pressure Monitor System" (TPMS) that GM added to its vehicle since 2008 or earlier. My first experience with TPMS was in a rented 2009 Chevy Impala that was reporting 26 PSI for the rear left tire (driver side) and 28 PSi for the others. I bought a mechanical tire gage and measured the air pressure in all four wheels, and none matched the TPMS readings on the dashboard display. The rear left tire had 29 PSI, and the others had 30 PSI, so I decided to add a bit of air pressure to the rear left until it was 31 PSI. The TPMS reading stayed at 26 and never went up. Since I trusted the gage, I ignores the TPMS readings. When I returned the Impala, I reported the problem, and the renter took the report and probably sent the Impala to its service area to fix it.
Now I have a 2009 Chevy Equinox (same year as the Impala), and its TPMS readings are always off by one or two PSI. So only trust the TPMS readings if the PSi drops quickly from one day to another. I prefer to read the pressures with the gage and check them weekly, then add pressure if the reading drops by 2 PSI. TPMS isn't trustworthy for exact pressure readings. I can only trust it as a warning for any prssure loss that is more than 2 PSI in any of the tires.
The Volt Owners Manual has a procedure to reset the TPMS reading per tire, but if that doesn't work, get your vehicle back to the dealer.