As an aside, Ford considers any mile that the engine is not running as "EV miles" on their plug-ins, even if their original battery charge has depleted, and that is very misleading. I believe they're the only ones that do this and, truthfully, I'm surprised they haven't been sued for deception.
The usage screen displays electric vs gas miles, not battery miles vs ICE is running miles. In terms of AER and MPGcs stats, those can’t be influenced much after the battery is fully depleted.
Perhaps Ford’s use of counting all battery miles as EV miles helps redirect driving techniques from statistics management to ICE-time management (i.e., if Volt displayed battery vs ICE is Running miles, you should get the same battery miles/kWh Used numbers for comparison with other electric cars, you just couldn’t monitor the kWh Used and AER per full charge numbers unless you fully depleted the battery prior to any ICE use).
Drive down a long steep hill with a fully depleted battery, and when you reach level ground, you have regen power in the battery you can use to drive for several miles. Does it matter to you, except for stats purposes, if those distances are counted as Electric or Gas miles? Because your battery was out of grid power and thus "fully depleted," the distances count as Gas Miles, and once the regen power is depleted, the ICE will start again.
Drive down the same hill in Hold mode, and the distances also count as Gas miles. Switch from Hold to Normal instead before heading down, and the distances count as Electric miles. No operational difference, but the mode choice influences the AER and MPGcs stats.
Or, with a fully depleted battery, switch to Mountain Mode, continue driving for ~10 minutes (Gen 2, ~20 minutes for Gen 1), switch back to Normal, and you’ll have ~2 bars (~4 bars for Gen 1) of power to fuel the primary electric motor for the price of the small amount of gas needed to generate that recharged power. Continue driving using that MM-recharged-from-full depletion power and most Volts will count the distances as Gas Miles. If you stop the car and turn it off and back on again after MM recharging, 2011/2012 Volts (and perhaps later models) will count the distances as Electric Miles. Does it matter, except as it influences the AER and MPGcs stats?