The AT-PZEV designation is an important designation in the CARB states. Basically it reroutes the exhaust, which will cut emissions by some very small amount but won't affect range or mileage or much of anything else. You can only buy Volts with this designation from dealers in CARB states and you have to register the car in a CARB state to get the extended warranty, which is the main plus. You can read more about it here: http://gm-volt.com/forum/showthread.php?14733-Battery-Warranty-10-yrs-150-000&p=160913#post160913
I don't know what the different AT-PZEV options are.
I don't know what the different AT-PZEV options are.