Is there anything that is imperative that I check on the car? With my Saturn is was ETCS + Motor Mounts, both went bad, and the fit was coils and cat with the latter being bad.
If you hear a *click* when accelerating and braking, it's the axle nuts. If you catch it early, it seems like re-torquing to spec fixes. If not, you'll probably need new nuts and bushings, MAYBE axle halves. All but the last are cheap.
If you start seeing wacky electrical/instrument stuff happening, your 12v AGM in the trunk is PROBABLY getting old and weak, and needs replacement. (The Volt uses the high voltage battery to actually start the engine, so you won't notice a cranking slowdown to warn you that the battery is getting old.) Don't believe unloaded battery tests that tell you it's okay.
The OEM tires always wear badly at the tread shoulder, even if you run them inflated to the sidewall maximum. Regrettable, but normal. They're also REALLY fragile sidewalls. Fear curbs or you WILL end up cutting one open sometime, and the little can of goo in the trunk won't fix that at all.
That's about it for the common problems. Everything else is pretty much in the manual. Read the manual. A lot. There are some very different things about this car.
Simple questions I'm sure, if I precondition 20 minutes before leaving, will I get most of the charge back if I'm using 120V 12AMP?
Nope. 240v 15amp level 2 can keep up with Eco heat. but not Comfort. You'll lose 2-3 miles of range with 120v. But that doesn't matter much anyway if you're driving less than 20 miles.
Also when it comes to long distance freeway driving (200 miles) when should I activate mountain mode? At 0 miles or at 12-16 miles?
Turn it on 20 minutes BEFORE you hit actual mountain inclines. The kinds of slopes where there's an extra lane for trucks. The ICE can cope just fine with a 1-2% grade, but will start tapping into the battery reserve for more than that. 20 minutes will be plenty to build up 40% charge, and that's plenty to handle everything in North America. But you don't even really need to worry too much -- if you forget, it'll just climb hills like the Fit did, and complain on the dashboard. Also, Hold and Mountain mode seem to have different levels of "aggression" about charging/maintaining their set points. Hold is more economical; Mountain is "No, I might need all the Go I can get for a while; caution to the wind, brother!" So your life will be more pleasant and marginally cheaper saving Mountain mode for actual mountains.