The Hyundai VP on the video is speaking imprecisely and you may be over interpreting his comments. The Ioniq hybrid’s 12v battery has its own dedicated physical cells in the hybrid battery pack assembly and it is electrically separate from the main hybrid cells. It is not literally using “any one of the LiIon battery’s sub-modules”.
Here’s a good overview from Car & Driver:
https://blog.caranddriver.com/how-t...ts-traditional-12v-lead-acid-starter-battery/