The Volt is an extended range electric vehicle, not a plug-in gas hybrid. That means when the battery is fully charged, your 2018 Volt will give you full performance using battery power only (charge depleting mode, the gas engine will not come on) until the charge level drops to a programmed level. At that point, the system switches to charge sustaining mode, and the gas engine will start (or you can switch to Hold Mode to engage CS mode). The 2018 Volt has three Extended Range Modes. Depending on driving conditions, speed, etc., the propulsion may be a blend of electric and gas propulsion, or just one or the other. When the system switches to gas use, generator output will be used to maintain the battery charge level, so the electric motor can make its contribution as needed... when extending the range the electric motor can use power from the battery buffer or from the generator output to provide its contribution to the propulsion.
The Volt is an extended range electric vehicle (motor uses battery only/battery supplemented by gas-generated electricity), so the function of the Energy Info display on the center console screen is to track the use of the fuel you buy (electricity from the utility company to charge the battery, gas from the gas station for the gas engine). "Electric Miles/kWh Used" records the distances driven using the "grid power" you get by charging the battery from the wall socket. "Gas Miles/Gal Used" records the distances driven in charge sustaining mode, when the engine burns gas to propel the car and/or to crank the generator.
Once the battery is depleted, you’ve used up the "grid power," so no more Electric Miles/kWh Used until you "buy more kWh," i.e., recharge from the wall again...
The regenerative braking system will put some charge back into the battery (especially if you drive down a long, steep hill). If that "regen" is created while driving in Electric Mode, then distances driven with the electric motor using that regen battery power will be counted as Electric Miles. If that regen is created while driving in Extended Range Mode (charge sustaining mode), the distances driven with the electric motor using that regen battery power will be counted as Gas Miles. In a Volt, a large number of the recorded "Gas Miles" may actually be distances driven using only the electric motor and battery power or generator output power.